It seems you might be referring to silicone condoms or perhaps condoms that are compatible with silicone-based lubricants. Here's a quick breakdown:
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Silicone Condoms: Most condoms are made from latex or polyisoprene, but silicone is often used in lubes and sex toys. Condoms themselves aren’t typically made of silicone, but you can safely use silicone-based lubricants with latex condoms.
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Using Silicone Lubricants: Silicone-based lubes are long-lasting and great for various types of play. Just ensure that the condom is compatible; latex condoms can generally be used with silicone lubes without any issues.